I would worry about introducing pests to your orchids, in particular slugs and snails, and possibly diseases, if using mosses gathered from the wild.
In bonsai culture the cultivation of mosses on the soil surface of display specimens use to be a really big deal. There was an entire method of collecting, grinding, sieving, sowing and watering the moss to create a uniform growth and appearance. But from what I've seen on the internet with today's bonsai culture, at least in America, I think the quick and easy choice is to just place bits and pieces of moss just before competition, instead of cultivating it over weeks or months. Still, this might be one area where you could get some ideas, especially a book or two about bonsai culture and display?
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