Well, it depends on how densly planted the wardian case vs. terrarium is... I think Orchid tanks are very sparsely populated compared to a moss covered vivarium... I mean, when you say that the plants run out of CO2 in 2 hours, how did you determine that CO2 was the limiting factor? You would need a CO2 measuring device to really tell... There probably aren't going to be scientific experiments on as small of a scale as our small cases.
Unfortunately the best "web info" you probably will find is on the pot growing forums, I really do try and stay away from them, but there is a ton of info on CO2 etc... in that realm if you don't mind drudging through those sites.
One cheap way we used to measure CO2, which is very inexpensive is a pH sensitive vial of colored liquid... When CO2 was available, it would turn pink (acid) and when it was not, it would turn blue (basic)... because CO2 + H20 = Carbonic Acid (forget the chemical formula)
Might try sticking one of those in your tank and see if it works, only 10$. Me personally, My tank is very leaky and I just dump tons of moisture in it, so air exchange isn't a concern. Reminds me of when I was a child and my neighbor and I were discussing why trees always died in one particular spot. I guessed it was "out of nutrients" my neighbor scoffed that dirt doesn't run out of nutrients... Not that either of us was a botanical expert (turns out it was too wet), but running out of CO2 seems difficult to me to comprehend.
CO2 Indicator - ThatPetPlace.com