I'll jump in with Ross... I was having some rotting problems from decomposing materials left over from the transplant, they were dying (my paphs and phals). I soaked with Thiomyl for about 20-30 minutes and then drained. Everything since then has been doing wonderful, I have used physan on occasion for some plants, just watered it like normal with it, or maybe held the holes closed for a few minutes while it soaked, then drained.
Thiomyl is powerful, so I wouldn't want to use it on any regular basis, but it certainly did a turn around job, all my paphs are growing spectacularly now compared to when they were maybe growing, but really just "surviving". Take the rot out, and you will see it's not necessarily the environment which is bad, but just decomposing material which needs to stop decomposing!
Pysan also has a nice side effect of discouraging algaes... not that they are bad, but unsightly, especially on open air roots like vandas...works wonders here and there. I got RD-20 instead of Physan 20, same thing basically.
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