Where are you growing your plant? I do not think this marking is connected to the loss of your old leaf.
This appears to be a bacterial infection from water sitting on the leaf during cold weather. Zygos are prone to this type of spotting/necrosis and if not kept in an environment with good air circulation and a warmer temp, this will happen. It is not pleasing to see but it does no permanent damage to the plant as a whole.
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