I haven't tried it with orchids, but we use mosquito dunks and bits with regular potting soil.
We've tried mixing the mosquito bits into the soil, putting a layer of the bits on the soil surface, and putting a mosquito dunk in the watering can overnight before watering. So long as we're consistent with using them until the gnats are gone and have been gone for a few weeks, it works.
The gnats come back if we stop using the dunks/bits and let the mix stay too wet. Thankfully it's only an occasional issue.
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