I can't say for sure that it is sunburn, but it still sure looks like it. Shifting sun can be insidious - you can have severe effects in a very short time. I have a story to illustrate, from my experience... I have a small greenhouse. Roof gives about 50% shade, so light is generally quite even, and mild. I have 4 vents, that open automatically based on temperature. The vents are covered in the same polycarbonate as the roof. I started noticing sunburn on the leaves of just a few plants, and couldn't figure out where it was coming from because I could not see any hot spots. Well, one very warm morning I just happened to be in there about 10 AM and saw a shaft of light come in through an east-facing open vent. Most of the time the vents were still closed when the sun was in that spot, but because of the heat, the vent was open and it came blasting in with no shading. For about 5 minutes. Then the sun got high enough to be above the vent and got shaded. But that 5 minutes was enough to toast leaves... and to catch it in the act I had to be there at just the right moment. (I added some very open shade cloth on the inside of the greenhouse covering the vent... solved the problem, still lets air in)
Your plants might have gotten a similar transient blast. It doesn't take long...
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