I use(d) an ultrasonic humidifier for a balcony area considerably larger than your proposed growing area; sadly they seem to die after about 6 months, and are quite expensive (over US$100 each). The ones I had have integrated humidistats, which is quite handy, but they only went as high as 75%, which is probably enough. There was also an option to run continuously regardless of humidity.
With regards to controlling your microclimate, one of those herpetological control units would probably work quite well. I would be tempted to use it to automate fans when hot and heater when cold; you can also use them to automate various humidification devices. I have no experience with these units, but they look quite nifty:
Digital Aquatics
I made my own "controller" out of industrial electromechanical doohickeys - a humidistat and a thermostat, along with a light sensor, relay (to "reverse" the light sensor, which turns on in the dark, which is the opposite of what I wanted for seasonal light signals) and a timer. Most of it was DIN rail mountable which was quite handy, and things that weren't were easily cable tied on there. It's a bit rough and ready, but it doesn't rain inside my house; I would ideally house it inside a plastic box with a small "muffin fan" continuously ventilating the enclosure. (There is already one blowing past the sensors). RS Components sell pretty much anything you might need for this.
RS Australia | World Leading Distributor of Electronics, Electromechanical and Industrial Components
With regards to ventilation/cooling, not only would I use forced air ventilation (perhaps having the inlet as a DIY or otherwise "wet wall), I would be sorely tempted to put in "just in case" greenhouse auto-openers on a panel.
You'll probably want some kind of shadecloth too, which ought to be mounted some distance above the polycarbonate.
Don't forget a few additional fans for turbulent flow inside the structure.