The RO system removes everything, at least down to a very low concentration, so in that sense it doesn't matter if you start with hard or softened water. Have no fear there.
Sometimes the volume of water used by an RO system can be a problem for a water softener, so they may be set up to draw unsoftened water. The RO system may go a little longer between maintenance with a softened water source though. Neither may be a big concern if your orchid collection isn't too big.
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