The roots are definitely starting to rot, good thing you caught it now. Echoing what others have said - just to emphasize the importance: Kelp extraxt (high in auxins) is fantastic when combined with fertilizer. The auxins help with the roots' intake of water and the nutrients from the fertilizer.
It only takes a few seconds for the roots to soak up available moisture (like they do in nature). Soaking longer is just a way to saturate the medium. Most Catts like to dry a bit between waterings and if they don't, the roots start to look like the ones in your pictures. Good luck!