Sunburn is by far not as dangerous as any other infection or infestation, and that leaf damage is nothing but a bit unsightly. A little patience will do it, and in the next flowering season you will not even think of it.
I would not throw it out or cut the leaf off. It's just a little spot and if you like the color of the flowers it is worth keeping. Most of my Orchids have a bit of sunburn, even with shadecloth I can not always avoid it in my climate.