They will bloom, provided everything else is good. 6500k is "daylight". The 3000k (red) is in the range that plants use while blooming, but nature doesn't change to this just when a plant blooms :-) Where you see these most often is when growing... other... plants.
What kind of fixture do you have and how many bulbs does it hold? I use both colors in my T5HO, but that's just my choice. Some people don't like how the red bulbs look and feel, so they don't use them at all. Because I use blue and red, it doesn't look bad to me, and I feel like I'm getting the best of both.
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