In my plant nutrition research lately, I found something of the basis for the "orchids cannot use urea directly" stuff. It is true...and false.
All plants have two absorption paths - roots and foliar. Foliar absorption is through areas of cells that are closely associated with stomata referred-to as "plasmodesmata". As orchids have evolved mechanisms to conserve water - fewer stomata, most stomata on the under-sides of leaves, thick (waxy) cuticles to prevent loss - foliar nutrient absorption is generally much less of a factor than with terrestrial plants, but it still varies with the plant.
The plasmodesmata tends to allow the transfer of nutrients into the leaves that are non-polar (like urea), but tends to not pass polar ionic species like nitrates and ammonium compounds.
Velamen on the roots, as I said before, has sites that specifically capture ions for absorption. By contrast, it is very poor at capturing less-polar chemicals like urea.
So the upshot is that orchids CAN use urea directly, but the absorption path is primarily foliar, although that tends to be limited in its absorptive capability. The urea has a much more difficult time of entering through the root system, so it must decompose before it can be used to an appreciable degree that way.
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