There are a few posts about diatomite on here that you can pull up on the OB search engine.
But yes, it does contain silica because it is a sedimentary rock that was formed mostly from silica from the remains of fossil diatoms.
All plants utilize silica to some degree or another in one way or another.
The Chemical Nature of Silica in Plants.
There are other articles you can look for regarding silica and plants.
Not all orchids respond well to the use of diatomite because of its capacity to store high quantities of water due to its high porosity.