Both RO and rain water are fine for your orchids, and room-temperature storage in plastic is fine.
As they are essentially pure, and nutrient-free, you will need to add a complete fertilizer with major-, minor-, and trace ingredients, or your plants could become deficient. Also please keep in mind that as neither water source is buffered, if you use fertilizer intended for mineral-laden tap water, your pH will likely be extremely acidic, so will need to be adjusted upward. An alternative is to use a formula intended for pure water in the first place.
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