It looks like the leaf tip may have sustained some minor damage. Also, while phals typically lose their lower leaves first, sometimes it’s a middle one that drops. I’ve noticed that when a leaf base has been punctured by enough new roots, it’s likely to drop regardless of where on the plant it’s located.
If only one leaf is affected, it’s not something I’d worry about at all. If more leaves start to show symptoms, check the roots.
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