I am mostly a beginner so take it with a grain of salt but, I’ve had some luck with thiomyl and copper for preventing or stopping rots (root and leaves) on non Dendrobium orchids I thought were at risk.
I also have aluminum tris (alliete) as a black rot preventative but I’m never sure if it works or not.
I think good cultural conditions in the first place usually means you won’t ever need these things but I like to keep them around to hedge my bets.
In terms of fertilizer, I usually go with something colloquially called “weakly weekly”. Essentially, use 1/5th-ish strength fertilizer every time you water. If you have outdoor tap water that is above 55f, you can buy a hose mixer and set it to the right quantity.
I am also very lazy so I often run out of mix and don’t refill it for a long time. My plants are “ok” but would probably do better if I was more diligent with the fertilizer. I also have kelpmax and calmag which are helpful as my water is pretty soft but I also forget to use them.
Right now my biggest focus is ridding my greenhouse of boisduval scale (which is next to impossible).
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