Welcome to the Orchid Board!
Don't panic with orchids, and don't fuss with them. It leads to mistakes. They grow slowly, so you shouldn't rip them up over and over, or change things rapidly.
Zygos are not the easiest orchids to grow in most homes. They like cool temperatures year round, even moisture and high humidity. Your conditions in the terrarium are good.
I don't see mold on the leaf. Is there mold that doesn't show in the photo? Do you see mycelial threads? I see a leaf dying. I don't know why the leaf died, but I don't see mold.
Zygos make a new growth, then flower. Then they make another new growth. The old growth will eventually die, but this is usually not for 1-3 years.
The single new growth was too small to separate. It may survive, but it is better to have 3-5 growths per division.
I think the single leaf dying may have been due to an older growth dropping a leaf in new surroundings. The roots look good. I would have slipped the plant out of the pot to look at the roots, then potted the whole thing into a slightly larger pot with a moisture-retentive potting mix. Fine bark works for some people; there are other possibilities. I would not have separated the new growth.
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