Hi Elliot,
I am not an expert in the field, but there is something we use to do in the lab in order to sterilize media that was possibly contaminated with fungi. Especially in those cases when we did not wanted to use chemicals... Just give the media a long bath (one our or so!), then drain it and let it rest covered for 12 - 24h(better overnight - this humid rest will activate all fungi spores, and possibly some dormant bacteria) then put it in the oven and 150 - 180ºC for 30 - 45 minutes, in order to kill all fungi and bacteria. You have to take care it does not burn and from time to time just move it thoroughly to have all media heated in the same way. Since you activated the spores before, you can be almost sure you will have no heat-resistant spores waiting to givve you a surprise later
I have never tried this with orchids... but it could work