I haven't had to soak orchids but I have soaked other plants for a few hours/overnight and ant activity does cease. I can't use systemic or toxic sprays on my indoor herbs, citrus, and other edibles so for these, I look for non-toxic alternatives (the other plants get the bayer rose systemic 3-in-one). I am into growing herbs and have tested many rumored to repel insects. The only one that I have found effective at discouraging bugs is a type of artemisia or 'wormwood' I grow (there are many). A few fresh leaves placed on top of a pot sends the ants scrambling. I haven't had ants moving into my orchids since I switched to lava rock and net pots but if I don't use the artemisia, the ants visit the plants.
In the winter, when the outdoor herbs are dormant, I use a combination of the soaking method, terro traps, and the systemic (on potted plants that are only ornamental). The most effective poison I have found for bugs is Sevin. It is toxic so should be used minimally and with care (on our fruit trees, it causes fruit drop--not certain if orchids are affected in any way). Good luck!
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