Interesting question-but why do you want to know. If its for cultivation - most of our orchids are epiphytic. Rainwater is slightly acidulous, because CO2 + H2O make H2CO3, pH 6,5 -6,8. Vulcanic eruptions can add sulphuric acid in low concentration. But for healthy growth all plants need some Calcium to strengthen the cells, also to counterbalance acidulous groups of rotting bark. Keep in mind that it is impossible to tell a pH for the milieu around the roots running along the bark of a tree. It is also impossible to measure the pH of a coarse orchid mix.
Only if the organic material (sphagnum, bark) decomposits, you can tell a pH. Then its unsuitable for potting epiphytic orchids.
Even plants from the so-called ant gardens, Gongorinae especially Coryanthes do better in standard mix. I´ve heard about people adding formic acid, but wouldn´t try myself.
For terrestrials things are different. Some paphis (niveum, bellatulum) grow on lime rocks. And conditions for germination of terrestric orchids are a scientific matter.
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