Actually, sheadog, I would recommend you do the opposite. A short soak (really more of a thorough rinse) in a very weak solution of Physan 20 (I think the package has directions for recommended concentration) is often a really good idea when deflasking seedlings. There are all kinds of fungal spores in the air that can quickly colonize and kill your tender baby orchids. Putting a small amount of Physan in the soaking water for the compot medium also works well. Even with Physan you may get some fungal problems, so make sure you have a fan in the room/GH to keep up good airflow.
As Philip indicated, the mycorrhizal fungi you have are unlikely to be of a type that are beneficial to orchids. And even if they're the right kind, these fungi can still quickly overgrow and kill your seedlings, especially if the plants are coming out of sterile asymbiotic flasks. Just my
, of course... Good luck!
--Nat