Orchideric is correct. I use a product called RD-20. It is EXACTLY the same composition as Phyan 20, just made by someone else and costs about the same. This is the manufacturer's lable about its use on ochids:
ORCHIDS
Seedlings: Soak seedling 2-5 minutes before potting to remove agar. To help prevent damping-off caused by Pythium, Fusarium or Rhizopus,
spray seedlings once per month as preventative maintenance. Spray any time disease is evident with a solution of 1.5 tsp. R-D-20
Greenhouse Disinfectant per gallon of water.
Adult Plants: Spray any time disease is evident with a solution of 2 tsp. R-D-20 Greenhouse Disinfectant per gallon of water. Spray once per
month as preventative maintenance.
Dividing Plants: Remove compost, then soak plans for minutes in a solution of 1 tbsp. R-D-20 Greenhouse Disinfectant per gallon of water.
Operate with wet hands and cutting tools. After division and root trim, soak divisions in the solution for 2 to 5 minutes. Pot in compost drenched
with the R-D-20 Greenhouse Disinfectant solution.
Botrytis Petal Blight: During cool weather, spray plants, flowers and under benches at first sign of spotting on flowers. Normally, weekly
sprayings will greatly reduce or eliminate the botrytis spotting. Use 1 tsp. of R-D-20 Greenhouse Disinfectant per 3 gallons of water.
Cut Flowers: containers. tubes and decorative vases. Recommend flower spikes be hardened in a solution of 1 tsp R-D-20 Greenhouse
Disinfectant per gallon of water during harvesting, storage and shipping to help control the transfer of diseases.
Rots (Such as Erwinia. et al): Remove compost from plant, then soak entire plant 10 minutes or more in a solution of 1 tbsp. R-D-20
Greenhouse Disinfectant per gallon of water. Cut away all rot with treated tool. Soak plant wounds again for 10 minutes in solution. Repot in
drenched compost.
Crown Rot: Spray plants weekly with a solution of 2 tsp. R-D-20 Greenhouse Disinfectant per gallon of water.
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