I think the CaCO3 and MgCO3 accumulating in the medium sets you up for two issues - high pH, and upsetting the osmotic balance, therefore drawing water from the root cells, both upsetting their internal chemistry.
I don't know what impact chelation would have, as that's intended to make a relatively insoluble ion more stable while in solution, so may play little role, if any, upon the process of drying, concentrating, and precipitating.
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